jmc

$BG$ is a diagonal along one face of the cube. Since this diagonal splits the square face into two $45-45-90$ triangles, the diagonal is $\sqrt{2}$ times longer than a side of the square, so a side of the square measures $5\sqrt{2}/\sqrt{2}=5$ units. Thus, the volume of the cube is $5^3=\boxed{125}$ cubic units.