jmc

Let the number of lollipops Joann ate on the first day be $a-12$, so she ate $a-6$ lollipops on the second day, $a$ on the third, and so on, eating $(a-12)+(5-1)\cdot 6=a+12$ lollipops on the last day. The total number of lollipops is $5a$, which we are told is 100. Thus, $5a=100$ and $a=20$. Since $a$ is the number of lollipops Joann ate on the third day, our answer is $\boxed{20}$ lollipops.