jmc

The two possible diagonal lengths are $AB$ and $AC$. The measure of an interior angle of a regular hexagon is $180(6-2)/6=120$ degrees. Therefore, angle $BCA$ measures $120/2=60$ degrees. Also, the base angles of the isosceles triangle with the marked 120-degree angle each measure $(180-120)/2=30$ degrees. This implies that $\angle CBA$ is a right angle, so triangle $ABC$ is a 30-60-90 triangle. Therefore, the ratio of $AB$ to $AC$ is $\boxed{\frac{\sqrt{3}}{2}}$.