jmc

For each integer $x$ in the list besides 5, the integer $10-x$ is also in the list. So, for each of these integers, removing $x$ reduces the number of pairs of distinct integers whose sum is 10. However, there is no other integer in list that can be added to 5 to give 10, so removing 5 from the list will not reduce the number of pairs of distinct integers whose sum is 10.

Since removing any integer besides 5 will reduce the number of pairs that add to 10, while removing 5 will leave the number of pairs that add to 10 unchanged, we have the highest probability of having a sum of 10 when we remove $\boxed{5}$.